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Publications

2024

42.

A. K. Jaiswal, P. Saha, J. Jiang, K. Suzuki, A. Jasny, B. M. Schmidt, S. Maeda,* S. Hecht,* C.-Y. Huang,* Accessing a Diverse Set of Functional Red-Light Photoswitches by Se-
lective Copper-Catalyzed Indigo N-Arylation, J. Am. Chem. Soc. 2024, 146, 21367–21376. Link

41.

T. Pausch, T. David, T. Fleck-Kunde, H. Pols, J. Gurke, B. M. Schmidt,* Multifold Post-Modification of Macrocycles and Cages by Isocyanate-Induced Azadefluorination Cyclisation, Angew. Chem. Int. Ed. 2024, 63, e202318362 Link  T. Pausch, T. David, T. Fleck-Kunde, H. Pols, J. Gurke, B. M. Schmidt,* Mehrfache Postmodifizierung von Makrozyklen und Käfigen durch Isocyanat-induzierte Azadefluorierungs-zyklisierung, Angew. Chem. 2024, 136, e202318362 Link 

2023

40.

E. Nieland, J. Voss, B. M. Schmidt,* Photoresponsive Supramolecular Cages and Macrocycles, ChemPlusChem 2023, 88, e202300353. Link

Invited Review
Including Frontispiece

39.

R. Küng, A. Germann, M. Krüsmann, L. P. Niggemann, J. Meisner, M. Karg, R. Göstl, B. M. Schmidt,* Mechanoresponsive Metal-Organic Cage-Crosslinked Polymer Hydrogels, Chem. Eur. J. 2023, 29, e202300079. Link

Highlighted in ChemistryViews Link

 

38.

E. Nieland, J. Voss,  B. M. Schmidt,* Shining A Light on Dissipative Supramolecular Assemblies, Synlett 2023, 34, 975-982. Link 

Invited contribution for SYNPACTS

 

37.

T. Fleck-Kunde, E. H. Wolpert, L. zur Horst, R. Oestreich, C. Janiak, K. E. Jelfs, B. M. Schmidt,* Observation of Rare Tri6Di9 Imine Cages Using Highly Fluorinated Building Blocks, Organic Materials 2022, 4, 255-260.  Link

 

36.

E. Nieland, J. Voss, A. Mix, B. M. Schmidt,* Photoresponsive Dissipative Macrocycles Using Visible-Light Switchable Azobenzenes, Angew. Chem. Int. Ed. 2022, 61, e202212745  Link  Photoresponsive dissipative Makrocyclen unter Verwendung von mit sichtbarem Licht schaltbaren Azobenzolen, Angew. Chem. 2022, 134, e202212745 Link

 

35.

S. Bügel, M. Hähnel, T. Kunde, N. de Sousa Amadeu, Y. Sun, A. Spieß, T. H. Y. Beglau, B. M. Schmidt,* C. Janiak,* Synthesis and Characterization of a Crystalline Imine-Based Covalent Organic Framework with Triazine Node and Biphenyl Linker and Its Fluorinated Derivate for CO2/CH4 Separation, Materials 2022, 15, 2807.  Link

Editor's Choice

 

34. E. Nieland, D. Komisarek, S. Hohloch, K. Wurst, V. Vasylyeva, O. Weingart,* B. M. Schmidt,* Supramolecular Networks by Imine Halogen Bonding, Chem. Commun. 2022, 58, 5233-5236 Link

 

33.

T. Kunde, T. Pausch, P. A. Guńka, M. Krzyżanowski, A. Kasprzak,* B. M. Schmidt,* Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state, Chem. Sci. 2022, 13, 2877-2883 . Link

Featured on the Front Cover Link

 

 

 

32. R. Küng, R. Göstl, B. M. Schmidt,* Release of Molecular Cargo from Polymer Systems by Mechanochemistry, Chem. Eur. J. 2022, 28, e202103860. Link

 

Invited Review
Including Frontispiece
Selected by the Editorial Office as outstanding Review

31. T. Kunde,+ T. Pausch,+ B. M. Schmidt,* Porous Organic Compounds – Small Pores on the Rise,  Eur. J. Org. Chem. 2021, 43, 5844-5856. Link

 

+:These authors contributed equally to this work.

Selected as Very Important Paper
Invited Review
Featured on the Front Cover
Link

30. T. Kunde,+ T. Pausch,+ B. M. Schmidt,* Supramolecular Alloys From Fluorinated Hybrid Tri4Di6 Imine Cages, Chem. Eur. J. 2021, 27, 8457-8460 . Link

 

+:These authors contributed equally to this work.

Selected as Hot Paper
Featured on the Front Cover Link

29. T. Kunde,+ T. Pausch,+ G. J. Reiss, B. M. Schmidt,* Highly Fluorinated Trianglimine Macrocycles – A Supramolecular Organic Framework (SOF), Synlett 2022, 30, 161-165. Link

Invited contribution to the themed issue "EuCheMS Organic Division Young Investigator" +:These authors contributed equally to this work.

Highlighted on the Front Cover
Highlighted in Synfacts 2021, 17, 871 by Timothy M. Swager and Yifan Wu Link

28. R. Küng, T. Pausch, D. Rasch, R. Göstl,* B. M. Schmidt,* Mechanochemical Release of Non-Covalently Bound Guests from a Polymer-Decorated Supramolecular Cage, Angew. Chem. 2021, 133, 13738-13742;  Link  PDF  Angew. Chem. Int. Ed. 2021, 60, 13626-13630;  Link  PDF  Pressemitteilung HHU  Press release of HHU

Selected as Hot Paper
Featured on the Front Cover
Link

2020

27. L. Helmecke, M. Spittler, B. M. Schmidt, C. Czekelius, Metal-free Iodoperfluoroalkylation: Photocatalysis vs. Frustrated Lewis Pair Catalysis, Synthesis 2020, 52, A-L. Link
26. T. Kunde, E. Nieland, H. V. Schröder, C. A. Schalley, B. M. Schmidt, A porous fluorinated organic [4+4] imine cage showing CO2 and H2 adsorption, Chem. Commun. 2020, 56, 4761-4764. Link  Front Cover  PDF

2019

25.

E. Nieland, O. Weingart, B. M. Schmidt, Fluorinated azobenzenes as supramolecular halogen-bonding building blocks, Beilstein J. Org. Chem. 2019, 15, 2013-2019. Link  PDF

(Invited contribution to the themed issue "Molecular Switches")

24. E. Nieland, T. Topornicki, T. Kunde, B. M. Schmidt, [2+2] Halogen-bonded boxes employing azobenzenes, Chem. Commun. 2019, 55, 8768-8771. Link  Front Cover (Inside)  Bernd's Emerging Investigator Profile
23. L. Hou, X. Zhang, G. F. Cotella, G. Carnicella, M. Herder, B. M. Schmidt, M. Pätzel, S. Hecht, F. Cacialli, P. Samorì, Optically switchable organic light-emitting transistors, Nat. Nanotechnol. 2019, 14, 347-353. Link  Press release of HU Berlin  Press release of HHU  Highlight in Nature
22. T. Kunde, B. M. Schmidt, Mikrokristalline Elektronenbeugung (MicroED) zur Strukturaufklärung niedermolekularer Verbindungen, Angew. Chem. 2019, 131, 676-678; Link  PDF Microcrystal Electron Diffraction (MicroED) for Small‐Molecule Structure Determination, Angew. Chem. Int. Ed. 2019, 58, 666-668. Link  PDF
 

2018

 
21. J. Niederhausen, Y. Zhang, F. Cheenicode Kabeer, Y. Garmshausen, B. M. Schmidt, Y. Li, K.-F. Braun, S. Hecht, A. Tkatchenko, N. Koch, S. W. Hla, Subtle Fluorination of Conjugated Molecules Enables Stable Nanoscale Assemblies on Metal Surfaces, J. Phys. Chem. C 2018, 122, 18902-18911. Link  PDF  
20.

F. Eisenreich, M. Kathan, A. Dallmann, S. P. Ihrig, T. Schwaar, B. M. Schmidt, S. Hecht, A photoswitchable catalyst system for remote-controlled (co)polymerization in situ. Nature Catalysis 2018, 1, 516-522.  Link  Front Cover  Pressemitteilung HU Berlin Press release of HHU  News & Views

 
19b. J. Gurke, Š. Budzák, B. M. Schmidt, D. Jacquemin, S. Hecht, Efficient Light-Induced pKa - Modulation coupled to Base-Catalyzed Photochromism. Angew. Chem. Int. Ed. 2018, 57, 4797-4801.  Link  PDF (Hot Paper)  
19a. J. Gurke, Š. Budzák, B. M. Schmidt, D. Jacquemin, S. Hecht, Effiziente lichtinduzierte pKa‐Modulation, gekoppelt mit basenkatalysierter Photochromie. Angew. Chem. 2018, 130, 4888-4893.  Link  PDF (Hot Paper)  
 

2017

 

18.

I. Birkenfelder, J. Gurke, L. Grubert, S. Hecht, B. M. Schmidt,* Click Chemistry Derived Pyridazines: Electron-Deficient Building Blocks with Defined Conformation and Packing Structure. Chem. Asian J. 2017, 12, 3156-3161.  Link  PDF  
17. C.-Y. Huang, A. Bonasera, L. Hristov, Y. Garmshausen, B. M. Schmidt, D. Jacquemin, S. Hecht, N,N'-Disubstituted Indigos as Readily Available Red-Light Photoswitches with Tunable Thermal Half-Lives. J. Am. Chem. Soc. 2017, 139, 15205-15211.  Link  PDF  
16. B. M. Schmidt,* A. K. Meyer, D. Lentz, Solid State Structures of Fluorine-rich Fluoranthenes. CrystEngComm. 2017, 19, 1328-1333. Link  PDF  
 

2016

 
15b. B. M. Schmidt, T. Osuga, T. Sawada, M. Hoshino, M. Fujita, Compressed Corannulene in a Molecular Cage. Angew. Chem. Int. Ed. 2016, 55, 1561-1564.  Link  PDF  
15a. B. M. Schmidt, T. Osuga, T. Sawada, M. Hoshino, M. Fujita, Corannulen komprimiert in einem molekularen Käfig. Angew. Chem. 2016, 128, 1587-159.  Link  PDF  
 

2015

 
14. M. Herder, B. M. Schmidt, L. Grubert, M. Pätzel, J. Schwarz, S. Hecht, Improving the Fatigue Resistance of Diarylethene Switches. J. Am. Chem. Soc. 2015, 137, 2738-2747.  Link  Highlighted by ChemistryViews  PDF  
 

2014

 
13. B. Topolinski, B. M. Schmidt, S. Schwagerus, M. Kathan, D. Lentz, Syntheses and Properties of Multiferrocenylated Corannulenes. Eur. J. Inorg. Chem. 2014, 5103-5106.  Link  PDF  
12.

B. M. Schmidt, D. Lentz, Syntheses and Properties of Buckybowls Bearing Electron-withdrawing Groups. Chem. Lett. 2014, 43, 171-177.  Link  Cover Picture  PDF

 
 

2013

 
11. B. M. Schmidt, B. Topolinski, M. Yamada, S. Higashibayashi, M. Shionoya, H. Sakurai, D. Lentz, Fluorinated and Trifluoromethylated Corannulenes. Chem. Eur. J. 2013, 19, 13872-13880.  Link  PDF  
10. B. Topolinski, B. M. Schmidt, S. Higashibayashi, H. Sakurai, D. Lentz, Sumanenylferrocenes and their solid state self-assembly. Dalton Trans. 2013, 42, 13809-1381.  Link  PDF  
9. B. M. Schmidt, B. Topolinski, S. Higashibayashi, T. Kojima, M. Kawano, D. Lentz, H. Sakurai, The Synthesis of Hexafluorosumanene and its Congeners. Chem. Eur. J. 2013, 19, 3282-3286.  Link  PDF  
 

2012

 
8b. B. M. Schmidt, S. Seki, B. Topolinski, K. Ohkubo, S. Fukuzumi, H. Sakurai, D. Lentz, Electronic Properties of Trifluoromethylated Corannulenes. Angew. Chem. Int. Ed. 2012, 51, 11385-11388.  Link  PDF  
8a. B. M. Schmidt, S. Seki, B. Topolinski, K. Ohkubo, S. Fukuzumi, H. Sakurai, D. Lentz, Elektronische Eigenschaften Trifluormethylierter Corannulene. Angew. Chem. 2012, 124, 11548-11551.  Link  PDF  
7. B. M. Schmidt, B. Topolinski, P. Roesch, D. Lentz, Electronpoor N-substituted Imide-fused Corannulenes. Chem. Commun. 2012, 48, 6520-6522.  Link  PDF  
6. B. Topolinski, B. M. Schmidt, M. Kathan, S. I. Troyanov, D. Lentz, Corannulenylferrocenes: Towards a 1D, Non-covalent Metal-organic Nanowire. Chem. Commun. 2012, 48, 6298-6300.  Link   PDF  
5. S. Mebs, M. Weber, P. Luger, B. M. Schmidt, H. Sakurai, S. Higashibayashi, S. Onogi, D. Lentz, Experimental electron density of sumanene, a bowl-shaped fullerene fragment; comparison with the related corannulene hydrocarbon. Org. Biomol. Chem. 2012, 10, 2218-2222.  Link  PDF  
4. S. Duric, B. M. Schmidt, N. M. Ninnemann, D. Lentz, C. C. Tzschucke, Synthesis of Trifluorostyrene Derivatives by Palladium-Catalyzed Cross-Coupling of Lithium Trimethoxy(trifluorovinyl)borate with Aryl Bromides. Chem. Eur. J. 2012, 18, 437-441.  Link  PDF  
 

2010 and before

 
3. S. El-Kurdi, A.-A. Al-Terkawi, B. M. Schmidt, A. Dimitrov, K. Seppelt, Tungsten(VI) and Tungsten(V) Fluoride Complexes. Chem. Eur. J. 2010, 16, 595-599.  Link  PDF  
2. S. Grabowsky, M. Weber, Y.-S. Chen, D. Lentz, B. M. Schmidt, M. Hesse, P. Luger, Electron Density of Corannulene from Synchrotron Data at 12 K, Comparison with Fullerenes. Z. Naturforsch. 2010, 65b, 452-460.  PDF  
1.

F. Ferrero, C. Lohrer, B. M. Schmidt, M. Noll, M. Malow, A mathematical model to predict the heating-up of large-scale wood piles. J. Loss Prev. Process Ind. 2009, 22, 439-448.  Link  PDF

 

 

 

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